Oz Clarke has led a panel to pick an England team of fizzes for the challenge, and the wines will face a New Zealand line-up selected by Jane Skilton MW.
The winning team will be selected by a panel of wine writers and cricket internationals at an event in Wellington on February 19, the day before England and New Zealand play in the cricket.
Guests at a second event to be held in London on the same day will choose a man of the match winner.
The events are being hosted by New Zealand Winegrowers and English Wine Producers.
Clarke said: “Both countries are now world-renowned for the quality of their fizz and to meet head-to-head in this keenly-anticipated match will certainly highlight the fabulous quality of these two nations’ wines.”