The link-up will run from March to June , during which time Stolichnaya will sponsor a radio show on Xfm - a regional station covering London, Manchester and Scotland.
Stolichnaya will also sponsor Music:Response shows as well as Xfm's unsigned band network Uploaded.
"Stoli is about authenticity, and this activity represents an authentic Russian vodka searching for the authentic sound of London, Manchester and Scotland," said Jo Spencer, head of marketing.
The deal will also include branded
on-air features, live event sponsorship and a new website - www.stoli-vodka.co.uk - which is scheduled to go live later this month.